Highly Selective Liquid-Phase Oxidation of Cyclohexane to KA Oil over Ti-MWW Catalyst: Evidence of Formation of Oxyl Radicals

Zhou, Wenjuan; Wischert, Raphaël; Xue, Kai; Zheng, Yuting; Albela, Belén; Bonneviot, Laurent; Clacens, Jean‐Marc; De Campo, Floryan; Pera‐Titus, Marc; Wu, Peng

doi:10.1021/cs400757j

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Highly Selective Liquid-Phase Oxidation of Cyclohexane to KA Oil over Ti-MWW Catalyst: Evidence of Formation of Oxyl Radicals

Published in ACS Catalysis • Nov 21, 2013

Authors:

Wenjuan Zhou

Raphaël Wischert

Kai Xue

Abstract

Various types of Ti-containing zeolites, i.e., Ti-MWW, TS-1, Ti-MOR, and Ti-BEA, have been evaluated as candidates for the liquid-phase oxidation of cyclohexane using t -butyl hydroperoxide (TBHP, 7–8 wt %) as model oxidant. Ti-MWW zeolite displayed the highest activity for cyclohexanol and cyclohex...

Subject

Cyclohexanol

Cyclohexane

Catalysis

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