Use of Originalω-Perfluorinated Dithioesters for the Synthesis of Well-Controlled Polymers by Reversible Addition-Fragmentation Chain Transfer (RAFT)

Lebreton, Pierre; Améduri, Bruno; Boutevin, Bernard; Corpart, Jean‐Marc

doi:10.1002/1521-3935(20020201)203:3<522::aid-macp522>3.0.co;2-l

Public

Use of Originalω-Perfluorinated Dithioesters for the Synthesis of Well-Controlled Polymers by Reversible Addition-Fragmentation Chain Transfer (RAFT)

Published in Macromolecular Chemistry and Physics • Feb 1, 2002

Authors:

Pierre Lebreton

Bruno Améduri

Bernard Boutevin

Abstract

A series of five fluorinated dithioesters PhC(S)SRCH2CnF2n+1 (where R represents an activating spacer and n = 6 or 8) was obtained in fair to high yields (57–88%). These transfer agents were successfully used in reversible addition-fragmentation transfer (RAFT) of styrene (S), methyl methacrylate (M...

Subject

Chain transfer

Reversible addition−fragmentation chain-transfer polymerization

Polymer chemistry

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