Two novel polyoxometalate (POM)-based metal-organic frameworks (MOFs), [TBA]3[ε-PMo(V)8Mo(VI)4O36(OH)4Zn4][BTB]4/3·xGuest (NENU-500, BTB = benzene tribenzoate, TBA(+) = tetrabutylammonium ion) and [TBA]3[ε-PMo(V)8Mo(VI)4O37(OH)3Zn4][BPT] (NENU-501, BPT = [1,1'-biphenyl]-3,4',5-tricarboxylate), were ...
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