Pd Nanoparticles Embedded into a Metal-Organic Framework: Synthesis, Structural Characteristics, and Hydrogen Sorption Properties

Zlotea, Claudia; Campesi, Renato; Cuevas, Fermín; Leroy, Éric; Dibandjo, Philippe; Volkringer, Christophe; Loiseau, Thierry; Férey, Gérard; Latroche, M.

doi:10.1021/ja9084995

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Pd Nanoparticles Embedded into a Metal-Organic Framework: Synthesis, Structural Characteristics, and Hydrogen Sorption Properties

Published in Journal of the American Chemical Society • Feb 15, 2010

Authors:

Claudia Zlotea

Renato Campesi

Fermín Cuevas

Abstract

The metal-organic framework MIL-100(Al) has been used as a host to synthesize Pd nanoparticles (around 2.0 nm) embedded within the pores of the MIL, showing one of the highest metal contents (10 wt %) without degradation of the porous host. Textural properties of MIL-100(Al) are strongly modified by...

Subject

Chemistry

Sorption

Hydride

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