Metal–Organic Replica of Fluorite Built with an Eight‐Connecting Tetranuclear Cadmium Cluster and a Tetrahedral Four‐Connecting Ligand

Chun, Hyungphil; Kim, Dongwoo; N. Dybtsev, Danil; Kim, Kimoon

doi:10.1002/anie.200353139

Public

Metal–Organic Replica of Fluorite Built with an Eight‐Connecting Tetranuclear Cadmium Cluster and a Tetrahedral Four‐Connecting Ligand

Published in Angewandte Chemie International Edition • Feb 11, 2004

Authors:

Hyungphil Chun

Dongwoo Kim

Danil N. Dybtsev

Abstract

A non-interpenetrating 3D metal–organic framework, synthesized by a solvothermal reaction of cadmium nitrate and a tetracarboxylate ligand, is the first metal–organic analogue of fluorite (CaF2). In the structure of the title compound, depicted, an eight-connecting tetranuclear cadmium cluster (gree...

Subject

Fluorite

Cadmium

Ligand (biochemistry)

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