Time Scale and Elementary Steps of CO‐Induced Disintegration of Surface Rhodium Clusters

Suzuki, Akane; Inada, Yasuhiro; Yamaguchi, Aritomo; Chihara, Teiji; Yuasa, Makoto; Nomura, Masaharu; Iwasawa, Yasuhiro

doi:10.1002/anie.200352318

Public

Time Scale and Elementary Steps of CO‐Induced Disintegration of Surface Rhodium Clusters

Published in Angewandte Chemie International Edition • Oct 8, 2003

Authors:

Akane Suzuki

Yasuhiro Inada

Aritomo Yamaguchi

Abstract

The disintegration of Rh clusters on an Al2O3 surface induced by CO, the elementary steps, and timescale of the reaction are analyzed for the first time by energy-dispersive X-ray absorption fine structure (DXAFS) at a time resolution of 100 ms (see picture). This study by the improved time-resolved...

Subject

Rhodium

Elementary reaction

Absorption (acoustics)

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