Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn<sup>2+</sup> Coordination Sites

Dincă, Mircea; Dailly, Anne; Liu, Yun; M. Brown, Craig; A. Neumann, Dan; R. Long, Jeffrey

doi:10.1021/ja0656853

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Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn2+ Coordination Sites

Published in Journal of the American Chemical Society • Dec 1, 2006

Authors:

Mircea Dincă

Anne Dailly

Yun Liu

Abstract

Use of the tritopic bridging ligand 1,3,5-benzenetristetrazolate (BTT3-) enables formation of [Mn(DMF)6]3[(Mn4Cl)3(BTT)8(H2O)12]2.42DMF.11H2O.20CH3OH, featuring a porous metal-organic framework with a previously unknown cubic topology. Crystals of the compound remain intact upon desolvation and show...

Subject

Chemistry

Microporous material

Hydrogen storage

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