Rhodium( I ) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction

Bontemps, Sébastien; Gornitzka, Heinz; Bouhadir, Ghenwa; Miqueu, Karinne; Bourissou, Didier

doi:10.1002/anie.200503649

Public

Rhodium( I ) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction

Published in Angewandte Chemie International Edition • Feb 9, 2006

Authors:

Sébastien Bontemps

Heinz Gornitzka

Ghenwa Bouhadir

Abstract

To and fro: Diphosphanylborane derivative 1 behaves as a tridentate, ambiphilic ligand towards rhodium(I) fragments (see picture). The presence of metal→borane interactions in the resulting square-pyramidal complexes is highlighted by structural analyses and DFT calculations.

Subject

Borane

Rhodium

Ligand (biochemistry)

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