A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re( i ) complexes

G. Hernández, José; A. J. Macdonald, Neil; Mottillo, Cristina; S. Butler, Ian; Friščić, Tomislav

doi:10.1039/c3gc42104j

Public

A mechanochemical strategy for oxidative addition: remarkable yields and stereoselectivity in the halogenation of organometallic Re( i ) complexes

Published in Green Chemistry • Nov 11, 2013

Authors:

José G. Hernández

Neil A. J. Macdonald

Cristina Mottillo

Abstract

A simple solvent-free mechanochemical procedure enables rapid and high-yielding oxidative halogenation of model organometallic Re(I) compounds with excellent and tunable stereoselectivity, demonstrating how mechanochemistry can advance and simplify fundamental organometallic transformations.

Subject

Stereoselectivity

Halogenation

Mechanochemistry

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