[Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick

Ahnfeldt, Tim; Guillou, Nathalie; Gunzelmann, Daniel; Margiolaki, Irene; Loiseau, Thierry; Férey, Gérard; Senker, Jürgen; Stock, Norbert

doi:10.1002/anie.200901409

Public

[Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick

Shared by NobleBlocks on Jun 25, 2009 • 12:00 AM UTC

Authors:

Tim Ahnfeldt

Nathalie Guillou

Daniel Gunzelmann

Abstract

Abstract Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12‐connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus fo...

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