[Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick

Ahnfeldt, Tim; Guillou, Nathalie; Gunzelmann, Daniel; Margiolaki, I.; Loiseau, Thierry; Férey, Gérard; Senker, Jürgen; Stock, Norbert

doi:10.1002/anie.200901409

Public

[Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick

Published in Angewandte Chemie International Edition • Jun 5, 2009

Authors:

Tim Ahnfeldt

Nathalie Guillou

Daniel Gunzelmann

Abstract

Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12-connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming dis...

Subject

Octahedron

Crystallography

Tetrahedron

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