Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

Šimon, Petr; De Proft, Frank; Jambor, Roman; Růžička, Aleš; Dostál, Libor

doi:10.1002/anie.201002209

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Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

Published in Angewandte Chemie International Edition • Jul 6, 2010

Authors:

Petr Šimon

Frank De Proft

Roman Jambor

Abstract

One on one: A combination of steric effects and MN interactions of a rigid NCN pincer ligand allows the isolation and characterization of monomeric stibinidene and bismuthinidene compounds. The structure and bonding was confirmed by crystallographic studies (see picture; Sb or Bi yellow, N blue) an...

Subject

Steric effects

Monomer

Ligand (biochemistry)

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