Recently Siegrist et al. proposed a structure for a high- T c superconductor Ba 2 YCu 3 O (9-∂) based on an orthorhombic ( a = a p , b = a p , c = 3 a p ) perovskitelike model containing Ba and Y cations ordered over the A -sites of the ABO 3 structure. This ordering is responsible for the tripling ...
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