Ligand‐Directed Strategy for Zeolite‐Type Metal–Organic Frameworks: Zinc(<scp>II</scp>) Imidazolates with Unusual Zeolitic Topologies

Huang, Xiao‐Chun; Lin, Yan‐Yong; Zhang, Jie‐Peng; Chen, Xiao‐Ming

doi:10.1002/anie.200503778

Public

Ligand‐Directed Strategy for Zeolite‐Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies

Published in Angewandte Chemie International Edition • Jan 27, 2006

Authors:

Xiao‐Chun Huang

Yan‐Yong Lin

Jie‐Peng Zhang

Abstract

Thermally robust porous metal–organic frameworks (MOFs) with zeolitic topologies were constructed by means of a ligand-directed strategy involving molecular tailoring of simple bridging imidazolates with coordinatively unimportant substituents. This led to the isolation of three new MOFs having unus...

Subject

Network topology

Zeolite

Ligand (biochemistry)

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