Transition‐Metal Complexes Featuring Z‐Type Ligands: Agreement or Discrepancy between Geometry and d n Configuration?

Sircoglou, Marie; Bontemps, Sébastien; Mercy, M.; Saffon, Nathalie; Takahashi, Masashi; Bouhadir, Ghenwa; Maron, Laurent; Bourissou, Didier

doi:10.1002/anie.200703518

Public

Transition‐Metal Complexes Featuring Z‐Type Ligands: Agreement or Discrepancy between Geometry and d n Configuration?

Published in Angewandte Chemie International Edition • Oct 8, 2007

Authors:

Marie Sircoglou

Sébastien Bontemps

M. Mercy

Abstract

The value of gold: The coordination of ambiphilic diphosphanylborane ligands to AuCl provides unusual square-planar gold(I) complexes. Insight is gained on the nature of the gold→borane interactions in these complexes through natural bond orbital (NBO) analysis and 197Au Mössbauer spectroscopy.

Subject

Geometry

Transition metal

Type (biology)

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