Synthesis and catalytic properties of MIL-100(Fe), an iron( <scp>iii</scp> ) carboxylate with large pores

Horcajada, Patricia; Surblé, Suzy; Serre, Christian; Hong, Do‐Young; Seo, You‐Kyong; Chang, Jong‐San; Grenèche, Jean−Marc; Margiolaki, I.; Férey, Gérard

doi:10.1039/b704325b

Public

Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores

Published in Chemical Communications • Jan 1, 2007

Authors:

Patricia Horcajada

Suzy Surblé

Christian Serre

Abstract

The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe)...

Subject

Carboxylate

Catalysis

Hydrothermal circulation

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