A Hexanuclear Iron(<scp>III</scp>) Carboxylate with an [Fe6(μ3‐O)3(μ2‐OH)]11+ Core as an Efficient Catalyst for Cycloalkane Oxidation

Trettenhahn, Günter; Nagl, Michael; Neuwirth, Norbert; B. Arion, Vladimir; Jary, Walther; Pöchlauer, Peter; Schmid, Walther

doi:10.1002/anie.200504406

Public

A Hexanuclear Iron(III) Carboxylate with an [Fe6(μ3‐O)3(μ2‐OH)]11+ Core as an Efficient Catalyst for Cycloalkane Oxidation

Published in Angewandte Chemie International Edition • Mar 20, 2006

Authors:

Günter Trettenhahn

Michael Nagl

Norbert Neuwirth

Abstract

Six of one: A hexanuclear iron p-nitrobenzoate compound (see structure; green Fe, red O, blue N, gray C), a novel type of iron cluster was prepared and characterized. The complex has an [Fe6(μ3-O)3(μ2-OH)]11+ core and shows a remarkable catalytic activity in the oxidation of cyclohexane.

Subject

Catalysis

Carboxylate

Cyclohexane

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