Tailoring the selectivity in 2-butene conversion over supported d0 group 4, 5 and 6 metal hydrides: from dimerization to metathesis

C. Szeto, Kaï; Merle, Nicolas; Rios, César; Rouge, Pascal; Llop Castelbou, Jessica; Taoufik, Mostafa

doi:10.1039/c5cy00582e

Public

Tailoring the selectivity in 2-butene conversion over supported d0 group 4, 5 and 6 metal hydrides: from dimerization to metathesis

Published in Catalysis Science & Technology • Jan 1, 2015

Authors:

Kaï C. Szeto

Nicolas Merle

César Rios

Abstract

2-Butenes are transformed in a continuous flow reactor over metal hydrides of zirconium, tantalum and tungsten supported on silica–alumina. Exceptionally high selectivity to dimeric products is obtained over supported zirconium hydride catalysts.

Subject

Selectivity

Zirconium

Tantalum

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