Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

Feng, Dawei; Gu, Zhi‐Yuan; Li, Jian‐Rong; Jiang, Hai‐Long; Wei, Zhang‐Wen; Zhou, Hong‐Cai

doi:10.1002/anie.201204475

Public

Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

Published in Angewandte Chemie International Edition • Aug 21, 2012

Authors:

Dawei Feng

Zhi‐Yuan Gu

Jian‐Rong Li

Abstract

Biomimetic MOF: Extremely stable MOFs with different open metal sites and ultra-large 1D channels, PCN-222 (Fe, Mn, Co, Ni, Cu, and Zn), have been assembled with eight-connected Zr6 clusters and redox-active metalloporphyrin motifs. PCN-222(Fe) shows peroxidase-like activity in aqueous solution, exh...

Subject

Zirconium

Metal-organic framework

Mesoporous material

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