Au <sup>I</sup> -catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene | NobleBlocks
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Au I -catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene
Published in Chemical Communications • Jan 1, 2006
Authors:
Nicolas Marion
,
Pierre de Frémont
,
Gilles Lemière
Abstract
The use of N-heterocyclic carbene (NHC) as a ligand in the gold(I)-catalyzed cycloisomerization of enyne results in the assembly of a new carbocyclic product.
