Exceptional chemical and thermal stability of zeolitic imidazolate frameworks

Sung Park, Kyo; Ni, Zheng; P. Côté, Adrien; Yong Choi, Jae; Huang, Rudan; J. Uribe‐Romo, Fernando; K. Chae, Hee; O’Keeffe, M.; M. Yaghi, Omar

doi:10.1073/pnas.0602439103

Public

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks

Published in Proceedings of the National Academy of Sciences • Jun 23, 2006

Authors:

Kyo Sung Park

Zheng Ni

Adrien P. Côté

Abstract

Twelve zeolitic imidazolate frameworks (ZIFs; termed ZIF-1 to -12) have been synthesized as crystals by copolymerization of either Zn(II) (ZIF-1 to -4, -6 to -8, and -10 to -11) or Co(II) (ZIF-9 and -12) with imidazolate-type links. The ZIF crystal structures are based on the nets of seven distinct ...

Subject

Imidazolate

Zeolitic imidazolate framework

Thermal stability

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