Detection and Identification of the Keto-Hydroperoxide (HOOCH<sub>2</sub>OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether

Moshammer, Kai; W. Jasper, Ahren; M. Popolan‐Vaida, Denisia; Lucassen, Arnas; Diévart, Pascal; Selim, Hatem; J. Eskola, Arkke; A. Taatjes, Craig; R. Leone, Stephen; Mani Sarathy, S.; Ju, Yiguang; Dagaut, Philippe; Kohse‐Höinghaus, Katharina; Hansen, Nils

doi:10.1021/acs.jpca.5b00101

Public

Detection and Identification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether

Published in The Journal of Physical Chemistry A • Feb 19, 2015

Authors:

Kai Moshammer

Ahren W. Jasper

Denisia M. Popolan‐Vaida

Abstract

In this paper we report the detection and identification of the keto-hydroperoxide (hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized intermediate species arising from the low-temperature (540 K) oxidation of dimethyl ether (DME). These observations were made possible by coup...

Subject

Chemistry

Dimethyl ether

Ether

Research Assistant

AI chat, annotations, notes & similar papers

Finding related papers...

Discussions

(0)

No comments yet

Be the first to share your thoughts!