A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules

Zhao, Jun; Wang, Ye-Nan; Dong, Wen‐Wen; Wu, Ya‐Pan; Li, Dong‐Sheng; Zhang, Qichun

doi:10.1021/acs.inorgchem.5b02294

Public

A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules

Published in Inorganic Chemistry • Mar 11, 2016

Authors:

Jun Zhao

Ye-Nan Wang

Wen‐Wen Dong

Abstract

A new luminescent terbium-metal-organic framework [Tb3(L)2(HCOO)(H2O)5]·DMF·4H2O (1) (H4L = 4,4'-(pyridine-3,5-diyl)diisophthalic acid) has been successfully assembled by Tb(3+) ions and an undeveloped pyridyl-tetracarboxylate. Compound 1 exhibits a 3D porous (3,8)-connected (4.5(2))2(4(2).5(12).6(6...

Subject

Chemistry

Nitromethane

Terbium

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