A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules.

J, Zhao; YN, Wang; WW, Dong; YP, Wu; DS, Li; QC, Zhang

doi:10.1021/acs.inorgchem.5b02294

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A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules.

Shared by NobleBlocks on Mar 11, 2016 • 12:00 AM UTC

Authors:

Zhao J

Wang YN

Dong WW

Abstract

A new luminescent terbium-metal-organic framework [Tb3(L)2(HCOO)(H2O)5]·DMF·4H2O (1) (H4L = 4,4'-(pyridine-3,5-diyl)diisophthalic acid) has been successfully assembled by Tb(3+) ions and an undeveloped pyridyl-tetracarboxylate. Compound 1 exhibits a 3D porous (3,8)-connected (4.5(2))2(4(2).5(12).6(6...

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