A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2.

M, Devillard; R, Declercq; E, Nicolas; AW, Ehlers; J, Backs; N, Saffon-Merceron; G, Bouhadir; JC, Slootweg; W, Uhl; D, Bourissou

doi:10.1021/jacs.6b01320

Public

A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2.

Shared by NobleBlocks on Mar 30, 2016 • 12:00 AM UTC

Authors:

Devillard M

Declercq R

Nicolas E

Abstract

Reaction of the geminal PAl ligand [Mes2PC(═CHPh)AltBu2] (1) with [Pt(PPh3)2(ethylene)] affords the T-shape Pt complex [(1)Pt(PPh3)] (2). X-ray diffraction analysis and DFT calculations reveal the presence of a significant Pt→Al interaction in 2, despite the strain associated with the four-membered ...

Discussions