K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

Wu, Hongping; Pan, Shilie; R. Poeppelmeier, Kenneth; Li, Hongyi; Jia, Dianzeng; Chen, Zhaohui; Fan, Xiaoyun; Yang, Yun; M. Rondinelli, James; Luo, Haosu

doi:10.1021/ja111083x

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K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

Published in Journal of the American Chemical Society • May 2, 2011

Authors:

Hongping Wu

Shilie Pan

Kenneth R. Poeppelmeier

Abstract

Introduction of the Cl(-) anion in the borate systems generates a new perovskite-like phase, K(3)B(6)O(10)Cl, which exhibits a large second harmonic response, about four times that of KH(2)PO(4) (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K(3)B(6)O(10)Cl crystallizes in ...

Subject

Chemistry

Perovskite (structure)

Absorption (acoustics)

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