Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N–H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane

Jacquet, Olivier; Das Neves Gomes, Christophe; Ephritikhine, M.; Cantat, Thibault

doi:10.1021/ja211527q

Public

Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N–H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane

Published in Journal of the American Chemical Society • Jan 31, 2012

Authors:

Olivier Jacquet

Christophe Das Neves Gomes

M. Ephritikhine

Abstract

A highly active organocatalytic system based on N-heterocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen molecules and heterocycles, using two chemical wastes: CO(2) and polymethylhydrosiloxane (PMHS).

Subject

Chemistry

Carbon dioxide

Formylation

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