Synthesis, characterization, and energetic properties of salts of the 1-cyanomethyl-1,1-dimethylhydrazinium cation.

Sabaté C, Miró; H, Delalu; E, Jeanneau

doi:10.1002/asia.201100994

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Synthesis, characterization, and energetic properties of salts of the 1-cyanomethyl-1,1-dimethylhydrazinium cation.

Shared by NobleBlocks on Mar 1, 2012 • 12:00 AM UTC

Authors:

Miró Sabaté C

Delalu H

Jeanneau E

Abstract

1,1-Dimethylhydrazine can be readily alkylated with bromoacetonitrile to form 1-cyanomethyl-1,1-dimethylhydrazinium bromide ([(CH(3))(2)N(CH(2)CN)NH(2)]Br, 1). The metathesis reaction of compound 1 led to the formation of a new family of energetic salts based on the [(CH(3))(2)N(CH(2)CN)NH(2)](+) ca...

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