A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO 2 Fixation and Regioselective and Enantioretentive Epoxide Activation

Beyzavi, Hudson; C. Klet, Rachel; Tussupbayev, Samat; Borycz, Joshua; A. Vermeulen, Nicolaas; J. Cramer, Christopher; Fraser Stoddart, J.; T. Hupp, Joseph; K. Farha, Omar

doi:10.1021/ja508626n

Public

A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO 2 Fixation and Regioselective and Enantioretentive Epoxide Activation

Published in Journal of the American Chemical Society • Oct 30, 2014

Authors:

Hudson Beyzavi

Rachel C. Klet

Samat Tussupbayev

Abstract

Porous heterogeneous catalysts play a pivotal role in the chemical industry. Herein a new Hf-based metal-organic framework (Hf-NU-1000) incorporating Hf6 clusters is reported. It demonstrates high catalytic efficiency for the activation of epoxides, facilitating the quantitative chemical fixation of...

Subject

Chemistry

Regioselectivity

Epoxide

Finding related papers...

Discussions

(0)

No comments yet

Be the first to share your thoughts!