Giant Ising-Type Magnetic Anisotropy in Trigonal Bipyramidal Ni(II) Complexes: Experiment and Theory

Ruamps, Renaud; Maurice, Rémi; Batchelor, L.J.; Boggio‐Pasqua, Martial; Guillot, Régis; Laure Barra, Anne; Liu, Junjie; Bendeif, El‐Eulmi; Pillet, Sébastien; Hill, Stephen; Mallah, Talal; Guihéry, Nathalie

doi:10.1021/ja308146e

Public

Giant Ising-Type Magnetic Anisotropy in Trigonal Bipyramidal Ni(II) Complexes: Experiment and Theory

Published in Journal of the American Chemical Society • Jan 24, 2013

Authors:

Renaud Ruamps

Rémi Maurice

L.J. Batchelor

Abstract

This paper reports the experimental and theoretical investigations of two trigonal bipyramidal Ni(II) complexes, [Ni(Me(6)tren)Cl](ClO(4)) (1) and [Ni(Me(6)tren)Br](Br) (2). High-field, high-frequency electron paramagnetic resonance spectroscopy performed on a single crystal of 1 shows a giant uniax...

Subject

Chemistry

Electron paramagnetic resonance

Trigonal bipyramidal molecular geometry

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