Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports

M. de Souza, Priscilla; C. Rabelo‐Neto, Raimundo; Eduardo Pizarro Borges, Luiz; Jacobs, Gary; H. Davis, Burtron; Sooknoi, Tawan; E. Resasco, Daniel; B. Noronha, Fábio

doi:10.1021/cs501853t

Public

Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports

Published in ACS Catalysis • Jan 15, 2015

Authors:

Priscilla M. de Souza

Raimundo C. Rabelo‐Neto

Luiz Eduardo Pizarro Borges

Abstract

The performance of Pd catalysts supported on SiO 2, Al 2 O 3 and ZrO 2 for the hydrodeoxygenation (HDO) of phenol has been compared in the gas phase, at 300 °C and 1 atm using a fixed bed reactor. While Pd supported on SiO 2 and Al 2 O 3 exhibits high selectivity to cyclohexanone, when supported on ...

Subject

Cyclohexanol

Hydrodeoxygenation

Cyclohexanone

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