Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification

We present the syntheses, structural characterization, gas sorption, I2 uptake, and magnetic properties of a double-walled porous metal-organic framework, [Co(II)3(lac)2(pybz)2]·3DMF (1·3DMF, purple, where pybz = 4-pyridyl benzoate, lac = d- and l-lactate) and of its post-synthetic modified (PSM) co... View More