Quantitative Measurements of HO2 and other products of n-butane oxidation (H2O2, H2O, CH2O, and C2H4) at elevated temperatures by direct coupling of a jet-stirred reactor with sampling nozzle and cavity ring-down spectroscopy (cw-CRDS).

Djehiche, Mokhtar; Linh Le Tan, Ngoc; D Jain, Chaithanya; Dayma, Guillaume; Dagaut, Philippe; Chauveau, Christian; Pillier, Laure; Tomas, Alexandre

doi:10.1021/ja510719k

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Quantitative Measurements of HO2 and other products of n-butane oxidation (H2O2, H2O, CH2O, and C2H4) at elevated temperatures by direct coupling of a jet-stirred reactor with sampling nozzle and cavity ring-down spectroscopy (cw-CRDS).

Published in Journal of the American Chemical Society • Nov 26, 2014

NobleIDark:/48914/w1/20260517/B155E570Record on NobleID

Authors:

Mokhtar Djehiche

,

Ngoc Linh Le Tan

,

Chaithanya D Jain

Abstract

For the first time quantitative measurements of the hydroperoxyl radical (HO2) in a jet-stirred reactor were performed thanks to a new experimental setup involving fast sampling and near-infrared cavity ring-down spectroscopy at low pressure. The experiments were performed at atmospheric pressure an...

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