Quantitative Measurements of HO2 and Other Products of n-Butane Oxidation (H2O2, H2O, CH2O, and C2H4) at Elevated Temperatures by Direct Coupling of a Jet-Stirred Reactor with Sampling Nozzle and Cavity Ring-Down Spectroscopy (cw-CRDS)

Djehiche, M.; Linh Le Tan, Ngoc; D. Jain, Chaithanya; Dayma, Guillaume; Dagaut, Philippe; Chauveau, Christian; Pillier, Laure; Tomas, Alexandre

doi:10.1021/ja510719k

Public

Quantitative Measurements of HO2 and Other Products of n-Butane Oxidation (H2O2, H2O, CH2O, and C2H4) at Elevated Temperatures by Direct Coupling of a Jet-Stirred Reactor with Sampling Nozzle and Cavity Ring-Down Spectroscopy (cw-CRDS)

Published in Journal of the American Chemical Society • Nov 8, 2014

Authors:

M. Djehiche

Ngoc Linh Le Tan

Chaithanya D. Jain

Abstract

For the first time quantitative measurements of the hydroperoxyl radical (HO2) in a jet-stirred reactor were performed thanks to a new experimental setup involving fast sampling and near-infrared cavity ring-down spectroscopy at low pressure. The experiments were performed at atmospheric pressure an...

Subject

Chemistry

Hydroperoxyl

Butane

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