Undirected Arene and Chelate‐Assisted Olefin C‐H Bond Activation: [Rh<sup>III</sup>Cp*]‐Catalyzed Dehydrogenative Alkene–Arene Coupling as a New Pathway for the Selective Synthesis of Highly Substituted <i>Z</i> Olefins

Wencel‐Delord, Joanna; Nimphius, Corinna; W. Patureau, Frédéric; Glorius, Frank

doi:10.1002/asia.201101018

Public

Undirected Arene and Chelate‐Assisted Olefin C‐H Bond Activation: [RhIIICp*]‐Catalyzed Dehydrogenative Alkene–Arene Coupling as a New Pathway for the Selective Synthesis of Highly Substituted Z Olefins

Published in Chemistry - An Asian Journal • Mar 2, 2012

Authors:

Joanna Wencel‐Delord

Corinna Nimphius

Frédéric W. Patureau

Abstract

Undirected/Directed Cross-Coupling: A new dehydrogenative RhIII-catalyzed cross-coupling reaction between bromoarenes bearing no directing group and vinylic substrates substituted by a chelating group is reported. An original reaction mechanism enables the use of internal alkenes in a Z-selective co...

Subject

Alkene

Chemistry

Chelation

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