Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity

Joost, Maximilian; Zeineddine, Abdallah; Estévez, Laura; Mallet‐Ladeira, Sonia; Miqueu, Karinne; Amgoune, Abderrahmane; Bourissou, Didier

doi:10.1021/ja506978c

Public

Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity

Published in Journal of the American Chemical Society • Sep 30, 2014

Authors:

Maximilian Joost

Abdallah Zeineddine

Laura Estévez

Abstract

Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild conditions and is general. The ensuing aryl gold(III) complexes have been characterized by spectroscopic and crystallographic means. DFT calcu...

Subject

Chemistry

Reactivity (psychology)

Aryl

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