UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation

Luo, Feng; Yan, Changsheng; Dang, Li‐Long; Krishna, Rajamani; Zhou, Wei; Wu, Hui; Dong, Xinglong; Han, Yu; Hu, Tong‐Liang; O’Keeffe, M.; Wang, Lingling; Luo, Ming‐Biao; Lin, Rui‐Biao; Chen, Banglin

doi:10.1021/jacs.6b02030

Public

UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation

Published in Journal of the American Chemical Society • Apr 26, 2016

Authors:

Feng Luo

Changsheng Yan

Li‐Long Dang

Abstract

A new metal-organic framework Zn2(H2O)(dobdc)·0.5(H2O) (UTSA-74, H4dobdc = 2,5-dioxido-1,4-benzenedicarboxylic acid), Zn-MOF-74/CPO-27-Zn isomer, has been synthesized and structurally characterized. It has a novel four coordinated fgl topology with one-dimensional channels of about 8.0 Å. Unlike met...

Subject

Chemistry

Separation (statistics)

Center (category theory)

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