Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis

Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when synthesized in the presence of monocarboxylic acid modulators under the most commonly employed conditions. We unequivocally demonstrate that missing cluster defects are the predominant defect and that their conc... View More