Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.

Q, Liao; A, Cavaillé; N, Saffon-Merceron; N, Mézailles

doi:10.1002/anie.201604812

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Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment.

Shared by NobleBlocks on Aug 4, 2016 • 12:00 AM UTC

Authors:

Liao Q

Cavaillé A

Saffon-Merceron N

Abstract

A homogeneous system which is able to yield silylamine from N2 and bis(silane) in one pot is reported. Mechanistically a {(triphosphine)molybdenum(I)} fragment, generated in situ, splits N2 into the corresponding nitrido complex at room temperature. Then, functionalization of the molybdenum nitrido ...

Subject

Nitrogen fixation

Molybdenum

Reduction

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