Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework

Milin, Eric; Patinec, Véronique; Triki, Smaı̈l; Bendeif, El‐Eulmi; Pillet, Sébastien; Marchivie, Mathieu; Chastanet, Guillaume; Boukheddaden, Kamel

doi:10.1021/acs.inorgchem.6b01081

Public

Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework

Published in Inorganic Chemistry • Jul 21, 2016

Authors:

Eric Milin

Véronique Patinec

Smaı̈l Triki

Abstract

We report a two-dimensional Hofmann-like spin-crossover (SCO) material, [Fe(trz-py) 2 {Pt(CN) 4 }]·3H 2 O, built from [FePt(CN) 4 ] layers separated by interdigitated 4-(2-pyridyl)-1,2,4,4 H -triazole (trz-py) ligands with two symmetrically inequivalent Fe II sites. This compound exhibits an incompl...

Subject

Spin crossover

Chemistry

Spin states

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