Quantification of the Keto-Hydroperoxide (HOOCH<sub>2</sub>OCHO) and Other Elusive Intermediates during Low-Temperature Oxidation of Dimethyl Ether.

K, Moshammer; AW, Jasper; DM, Popolan-Vaida; Z, Wang; Shankar VS, Bhavani; L, Ruwe; CA, Taatjes; P, Dagaut; N, Hansen

doi:10.1021/acs.jpca.6b06634

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Quantification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Elusive Intermediates during Low-Temperature Oxidation of Dimethyl Ether.

Shared by NobleBlocks on Oct 4, 2016 • 12:00 AM UTC

Authors:

Moshammer K

Jasper AW

Popolan-Vaida DM

Abstract

This work provides new temperature-dependent mole fractions of elusive intermediates relevant to the low-temperature oxidation of dimethyl ether (DME). It extends the previous study of Moshammer et al. [ J. Phys. Chem. A 2015 , 119 , 7361 - 7374 ] in which a combination of a jet-stirred reactor and ...

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