Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH<sub>3</sub>)<sub>2</sub>COO

Chhantyal‐Pun, Rabi; Welz, Oliver; D. Savee, John; J. Eskola, Arkke; P. F. Lee, Edmond; Blacker, Lucy; R. Hill, Henry; Ashcroft, Matilda; Anwar H. Khan, M.; C. Lloyd‐Jones, Guy; A. Evans, Louise; Rotavera, Brandon; Huang, Haifeng; L. Osborn, David; Kam‐Wah Mok, Daniel; M. Dyke, John; E. Shallcross, Dudley; J. Percival, Carl; J. Orr‐Ewing, Andrew; A. Taatjes, Craig

doi:10.1021/acs.jpca.6b07810

Public

Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO

Published in The Journal of Physical Chemistry A • Oct 18, 2016

Authors:

Rabi Chhantyal‐Pun

Oliver Welz

John D. Savee

Abstract

The Criegee intermediate acetone oxide, (CH 3 ) 2 COO, is formed by laser photolysis of 2,2-diiodopropane in the presence of O 2 and characterized by synchrotron photoionization mass spectrometry and by cavity ring-down ultraviolet absorption spectroscopy. The rate coefficient of the reaction of the...

Subject

Kinetics

Chemistry

Chemical kinetics

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