Solid‐State Emission of the Anthracene‐<i>o</i>‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State

Naito, Hirofumi; Nishino, Kenta; Morisaki, Yasuhiro; Tanaka, Kazuo; Chujo, Yoshiki

doi:10.1002/anie.201609656

Public

Solid‐State Emission of the Anthracene‐o‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State

Published in Angewandte Chemie International Edition • Dec 1, 2016

Authors:

Hirofumi Naito

Kenta Nishino

Yasuhiro Morisaki

Abstract

The emission process of the o-carborane dyad with anthracene originating from the twisted intramolecular charge transfer (TICT) state in the crystalline state is described. The anthracene-o-carborane dyad was synthesized and its optical properties were investigated. Initially, the dyad had aggregati...

Subject

Intramolecular force

Anthracene

Carborane

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