A joint experimental and theoretical study is presented for the electronic structures of copper oxides including $\mathrm{C}{\mathrm{u}}_{2}\mathrm{O}$, CuO, and the metastable mixed-valence oxide $\mathrm{C}{\mathrm{u}}_{4}{\mathrm{O}}_{3}$. The optical band gap is determined by experimental optica...
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