New mechanistic interpretations for nitrone reactivity.
Published in Organic & biomolecular chemistry • Apr 18, 2017
Authors:,,
Pedro Merino
Tomás Tejero
Ignacio Delso
Abstract
The reactivity of nitrones in cycloadditions and related reactions is revisited by introducing a topological perspective. In particular, the study of electron localization function (ELF) along a reaction pathway allows evaluating bond reorganization showing that in several cases the bonds are formed...
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