Probing
Frontier Orbital Energies of {Co9(P2W15)3} Polyoxometalate Clusters
at Molecule–Metal and Molecule–Water Interfaces

Yi, Xiaofeng; V. Izarova, Natalya; Stuckart, Maria; Guérin, David; Thomas, Louis; Lenfant, Stéphane; Vuillaume, Dominique; van Leusen, Jan; Duchoň, Tomáš; Nemšák, Slavomír; D. M. Bourone, Svenja; Schmitz, Sebastian; Kögerler, Paul

doi:10.1021/jacs.7b07034

Public

Probing Frontier Orbital Energies of {Co9(P2W15)3} Polyoxometalate Clusters at Molecule–Metal and Molecule–Water Interfaces

Shared by NobleBlocks on Sep 13, 2017 • 12:00 AM UTC

Authors:

Xiaofeng Yi

Natalya V. Izarova

Maria Stuckart

Abstract

Abstract Functionalization of polyoxotungstates with organoarsonate coligands enabling surface decoration was explored for the triangular cluster architectures of the composition [CoII9(H2O)6(OH)3(p-RC6H4AsVO3)2(α-PV2WVI15O56)3]25– ({Co9(P2W15)3}, R = H or NH2), isolated as Na25[Co9(OH)3(H2O)6(C6H5A...

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