Defibrillation of soft porous metal-organic frameworks with electric fields

Knebel, Alexander; Geppert, Benjamin; Volgmann, Kai; I. Kolokolov, Daniil; G. Stepanov, Alexander; Twiefel, Jens; Heitjans, Paul; Volkmer, Dirk; Caro, J.

doi:10.1126/science.aal2456

Public

Defibrillation of soft porous metal-organic frameworks with electric fields

Published in Science • Oct 19, 2017

Authors:

Alexander Knebel

Benjamin Geppert

Kai Volgmann

Abstract

Gas transport through metal-organic framework membranes (MOFs) was switched in situ by applying an external electric field (E-field). The switching of gas permeation upon E-field polarization could be explained by the structural transformation of the zeolitic imidazolate framework ZIF-8 into polymor...

Subject

Porosity

Metal-organic framework

Electric field

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