A Fully Noble Metal-Free Photosystem Based on Cobalt-Polyoxometalates Immobilized in a Porphyrinic Metal-Organic Framework for Water Oxidation.

G, Paille; M, Gomez-Mingot; C, Roch-Marchal; B, Lassalle-Kaiser; P, Mialane; M, Fontecave; C, Mellot-Draznieks; A, Dolbecq

doi:10.1021/jacs.7b11788

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A Fully Noble Metal-Free Photosystem Based on Cobalt-Polyoxometalates Immobilized in a Porphyrinic Metal-Organic Framework for Water Oxidation.

Shared by NobleBlocks on Feb 2, 2018 • 12:00 AM UTC

Authors:

Paille G

Gomez-Mingot M

Roch-Marchal C

Abstract

The sandwich-type polyoxometalate (POM) [(PW9O34)2Co4(H2O)2]10- was immobilized in the hexagonal channels of the Zr(IV) porphyrinic MOF-545 hybrid framework. The resulting composite was fully characterized by a panel of physicochemical techniques. Calculations allowed identifying the localization of...

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