Bismuth as a versatile cation for luminescence in coordination polymers from BiX<sub>3</sub>/4,4'-bipy: understanding of photophysics by quantum chemical calculations and structural parallels to lanthanides.

JR, Sorg; T, Wehner; PR, Matthes; R, Sure; S, Grimme; J, Heine; K, Müller-Buschbaum

doi:10.1039/c8dt00642c

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Bismuth as a versatile cation for luminescence in coordination polymers from BiX3/4,4'-bipy: understanding of photophysics by quantum chemical calculations and structural parallels to lanthanides.

Shared by NobleBlocks on Jun 1, 2018 • 12:00 AM UTC

Authors:

Sorg JR

Wehner T

Matthes PR

Abstract

Coordination polymers (CPs) with bismuth(iii) as a connectivity centre have been prepared from BiX3 (X = Cl-I) and 4,4'-bipyridine (bipy) in order to implement Bi-based luminescence. The products were obtained via different synthetic routes such as solution chemistry, melt syntheses or mechanochemic...

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