Post‐Synthetic Ligand Exchange in Zirconium‐Based Metal–Organic Frameworks: Beware of The Defects!

Taddei, Marco; J. Wakeham, Russell; Koutsianos, Athanasios; Andreoli, Enrico; R. Barron, Andrew

doi:10.1002/anie.201806910

Public

Post‐Synthetic Ligand Exchange in Zirconium‐Based Metal–Organic Frameworks: Beware of The Defects!

Published in Angewandte Chemie International Edition • Jul 10, 2018

Authors:

Marco Taddei

Russell J. Wakeham

Athanasios Koutsianos

Abstract

H NMR spectroscopy. Samples of UiO-66 having different degrees of defectivity were exchanged using solutions of several terephthalic acid analogues in a range of conditions. Linker exchange only occurred in defect-free UiO-66, whereas monocarboxylates grafted at defect sites were found to be prefere...

Subject

Zirconium

Metal-organic framework

Ligand (biochemistry)

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