On the alcoholysis of alkyl-aluminum( <scp>iii</scp> ) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair <i>versus</i> Al-alkyl

Dardun, Vincent; Escomel, Léon; Jeanneau, Erwann; Camp, Clément

doi:10.1039/c8dt01498a

Public

On the alcoholysis of alkyl-aluminum( iii ) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl

Published in Dalton Transactions • Jan 1, 2018

Authors:

Vincent Dardun

Léon Escomel

Erwann Jeanneau

Abstract

Alkyl-aluminum( iii ) derivatives supported by a bifunctional alkoxy-NHC ligand display unusual reactivity at the carbene, yielding imidazolium-aluminate zwitterions.

Subject

Carbene

Alkyl

Reactivity (psychology)

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