A rare three-dimensional POM-based inorganic metal polymer bonded by CO<sub>2</sub> with high catalytic performance for CO<sub>2</sub> cycloaddition.

W, Cheng; YS, Xue; XM, Luo; Y, Xu

doi:10.1039/c8cc07041e

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A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition.

Shared by NobleBlocks on Nov 1, 2018 • 12:00 AM UTC

Authors:

Cheng W

Xue YS

Luo XM

Abstract

An exceedingly rare three-dimensional CO2-coordinated inorganic polyoxoanion was prepared by a hydrothermal synthesis reaction. The CO2 ligand connects with two Zn-ε-Keggin cores in a linear and symmetrical μ2-η2o,o coordination pattern with a C[double bond, length as m-dash]O bond length of 1.099(1...

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