Phase Separation and Self-Assembly in Vitrimers: Hierarchical Morphology of Molten and Semicrystalline Polyethylene/Dioxaborolane Maleimide Systems

G. Ricarte, Ralm; Tournilhac, François; Leibler, Ludwik

doi:10.1021/acs.macromol.8b02144

Public

Phase Separation and Self-Assembly in Vitrimers: Hierarchical Morphology of Molten and Semicrystalline Polyethylene/Dioxaborolane Maleimide Systems

Published in Macromolecules • Dec 28, 2018

Authors:

Ralm G. Ricarte

François Tournilhac

Ludwik Leibler

Abstract

Vitrimers are a class of polymers that flow when heated but are insoluble. Vitrimers are made of covalent networks with dynamic links and/or cross-links that undergo an associative exchange reaction. These dynamic cross-links enable vitrimers to have interesting mechanical/rheological behavior, self...

Subject

Maleimide

Crystallinity

Morphology (biology)

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